城西大学機関リポジトリJURAAdamantylidene Addition to M3N@Ih-C80 (M=Sc, Lu) and Sc3N@D5h-C80: Synthesis and Crystallographic Characterization of the [5,6]-Open and [6,6]-Open Adducts

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Adamantylidene Addition to M3N@Ih-C80 (M=Sc, Lu) and Sc3N@D5h-C80: Synthesis and Crystallographic Characterization of the [5,6]-Open and [6,6]-Open Adducts

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ID	JOS-chem.201700049
著者：名前	Yamada, Michio/阿部, 玄之/Saito, Chiharu/Yamazaki, Toshiki/Sato, Satoru/溝呂木, 直美/Slanina, Zdenek/Uhl&k, Filip/鈴木, 光明/前田, 優/Lian, Yongfu/Lu, Xing/Olmstead, Marilyn M./Balch, Alan L./永瀬, 茂/赤阪, 健
著者：別形式	Yamada, Michio / Abe, Tsuneyuki / Saito, Chiharu / Yamazaki, Toshiki / Sato, Satoru / Mizorogi, Naomi / Slanina, Zdenek / Uhl&k, Filip / Suzuki, Mitsuaki / Maeda, Yutaka / Lian, Yongfu / Lu, Xing / Olmstead, Marilyn M. / Balch, Alan L. / Nagase, Shigeru / Akasaka, Takeshi
著者：カナ	ヤマダ, ミチオ/アベ, ツネユキ/サイトウ, チハル/ヤマザキ, トシキ/サトウ, サトル/ミゾロギ, ナオミ/Slanina, Zdenek/Uhl&k, Filip/スズキ, ミツアキ/マエダ, ユタカ/Lian, Yongfu/Lu, Xing/Olmstead, Marilyn M./Balch, Alan L./ナガセ, シゲル/アカサカ, タカシ
著者：所属	東京学芸大学化学科 / 筑波大学生命領域学際研究センター / 筑波大学生命領域学際研究センター / 筑波大学生命領域学際研究センター / 筑波大学生命領域学際研究センター / 筑波大学生命領域学際研究センター / National Chung-Cheng University, Department of Chemistry and Biochemistry / Charles University, Department of Physical and Macromolecular Chemistry / 城西大学理学部化学科 / 東京学芸大学化学科 / Heilongjiang University, School of Chemistry and Materials Science, Ministry of Education, Key Laboratory of Functional Inorganic Material Chemistry / Huazhong University of Science and Technology, School of Materials Science and Engineering, State Key Laboratory of Materials Processing and Die and Mold Technology / University of California, Department of Chemistry / University of California, Department of Chemistry / 京都大学福井謙一記念研究センター / 東京学芸大学化学科
著者：所属(別形式）	Tokyo Gakugei University, Department of Chemistry / University of Tsukuba, Life Science Center of Tsukuba Advanced Research Alliance / University of Tsukuba, Life Science Center of Tsukuba Advanced Research Alliance / University of Tsukuba, Life Science Center of Tsukuba Advanced Research Alliance / University of Tsukuba, Life Science Center of Tsukuba Advanced Research Alliance / University of Tsukuba, Life Science Center of Tsukuba Advanced Research Alliance / National Chung-Cheng University, Department of Chemistry and Biochemistry / Charles University, Department of Physical and Macromolecular Chemistry / Josai University, Department of Chemistry, Faculty of Science / Tokyo Gakugei University, Department of Chemistry / Heilongjiang University, School of Chemistry and Materials Science, Ministry of Education, Key Laboratory of Functional Inorganic Material Chemistry / Huazhong University of Science and Technology, School of Materials Science and Engineering, State Key Laboratory of Materials Processing and Die and Mold Technology / University of California, Department of Chemistry / University of California, Department of Chemistry / Kyoto University, Fukui Institute for Fundamental Chemistry / Tokyo Gakugei University, Department of Chemistry
著者版フラグ	author
出版地	Hoboken
出版者	Wiley
冊子ISSN	09476539
電子ISSN	15213765
掲載誌名	Chemistry A European Journal
巻	23
号	27
刊行年月	20170511
開始ページ	6552
終了ページ	6561
コンテンツ作成日	2017-01-04
コンテンツ修正日	2017-02-01
コンテンツ登録日	2018-07-31
識別番号：DOI	info:doi/10.1002/chem.201700049
識別番号：DOI（リンク）	https://doi.org/10.1002/chem.201700049
抄録	Additions of adamantylidene (Ad) to M3N@Ih‐C80 (M=Sc, Lu) and Sc3N@D5h‐C80 have been accomplished by photochemical reactions with 2‐adamantyl‐2,3′‐[3H]‐diazirine (1). In M3N@Ih‐C80, the addition led to rupture of the [6,6]‐ or [5,6]‐bonds of the Ih‐C80 cage, forming the [6,6]‐open fulleroid as the major isomer and the [5,6]‐open fulleroid as the minor isomer. In Sc3N@D5h‐C80, the addition also proceeded regioselectively to yield three major isomeric Ad mono‐adducts, despite the fact that there are nine types of C−C bonds in the D5h‐C80 cage. The molecular structures of the seven Ad mono‐adducts, including the positions of the encaged trimetallic nitride clusters, have been unambiguously determined through single‐crystal XRD analyses. Furthermore, results have shown that stepwise addition of Ad to Lu3N@Ih‐C80 affords several Ad bis‐adducts, two of which have been isolated and characterized. The X‐ray structure of one bis‐adduct clearly revealed that the second Ad addition took place at a [6,6]‐bond close to an endohedral metal atom. Theoretical calculations have also been performed to rationalize the regioselectivity.
キーワード	cycloaddition/fullerenes/rare earths/regioselectivity/X-ray diffraction
言語	eng
資源タイプ	text
ジャンル	01学術雑誌論文 / Journal Article
フォーマット	application/pdf
権利	Copyright © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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このアイテムを表示する：URI	http://libir.josai.ac.jp/il/meta_pub/G0000284repository_JOS-chem.201700049

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