| ID | JOS-1347-4065_ab97ed |
| 著者：名前 | |
| 著者：別形式 | Nanzan, Chika / Takazawa, Yorimasa / Suzuki, Mitsuaki / Teramae, Hiroyuki / Sakata,Tomomi |
| 著者：カナ | |
| 著者：所属 | 城西大学理学部化学科 / 城西大学理学部化学科 / 城西大学理学部化学科 / 城西大学理学部化学科 / 城西大学理学部化学科 |
| 著者：所属(別形式） | Josai University, Faculty of Science, Department of Chemistry / Josai University, Faculty of Science, Department of Chemistry / Josai University, Faculty of Science, Department of Chemistry / Josai University, Faculty of Science, Department of Chemistry / Josai University, Faculty of Science, Department of Chemistry |
| 著者版フラグ | author |
| 出版地 | Tokyo |
| 出版者 | Japan Society of Applied Physics |
| 出版者：別名 | 応用物理学会 |
| 冊子ISSN | 00214922 |
| 電子ISSN | 13474065 |
| 掲載誌名 | |
| 巻 | 59 |
| 号 | 7 |
| 刊行年月 | 2020-06 |
| 開始ページ | 077001-1 |
| 終了ページ | 077001-7 |
| コンテンツ作成日 | 2020-04-02 |
| コンテンツ修正日 | 2020-05-29 |
| コンテンツ登録日 | 2021-07-20 |
| 識別番号：DOI | info:doi/10.35848/1347-4065/ab97ed |
| 識別番号：DOI（リンク） | |
| 抄録 | The [Cu2Br2(DIB)2(PPh2)2]n complex, obtained by the reaction between [Cu4Br4(PPh3)4] and 1,4-diisocyanobenzene (DIB), was found to have a bridged polymeric structure with a planar {Cu2Br2} core. The compound exhibited bluish-green (λmax = 498 nm) and green (λmax = 515 nm) luminescence at 295 and 77 K, respectively, corresponding to the emissions from XLCT (HE band) and (X + M)LCT (LE band), respectively. The dual emission, which is attributed to the luminescence from both bands, was observed at around 178 K. The complex also displayed a change in luminescence color from bluish-green to yellow (λmax = 529 nm) upon applying external mechanical stimuli. The film containing [Cu2Br2(DIB)2(PPh2)2]n was prepared by a cast method using polymethyl methacrylate as a binding agent. The rubbed part of the film turned yellow and the other parts maintained bluish-green luminescence. Restoration of the initial color was feasible by annealing, even in film state. |
| キーワード | |
| 注記 | 7p. ORCID iDs Mitsuaki Suzuki https://orcid.org/0000-0001-7226-2665 |
| 言語 | eng |
| 資源タイプ | text |
| ジャンル | |
| フォーマット | application/pdf |
| 権利 | Copyright © 2020 The Japan Society of Applied Physics |
| このアイテムを表示する：本文(pdf) |  ダウンロード回数： 回 |
| このアイテムを表示する：URI | |
